Transcaer anhydrous ammonia training anhydrous ammonia properties. As a result, many engineers chose to continue to use the old data. Oil or other combustible materials increases the fire hazard. In agriculture, ammonia can be used for crop processing, fertilizers, or as an antifungal treatment for citrus.
Product identifier product name ammonia solution 24,9% chemical name amonium hydroxide synonyms ammonia solution, ammonia water cas no. Flush skin with copious amounts of tepid water for a minimum of 20 minutes. Classified according to the unghs as adopted in the us hazard communication standard hcs. Anhydrous ammonia reacts to form explosive products, mixtures or compounds with mercury, gold, silver, iodine, bromine, silver oxide and silver chloride. Seek medical advice if discomfort or irritation persists. Do not rub or apply topical, occlusive compounds, such as ointments, certain creams, etc. Anhydrous ammonia decomposes to hydrogen and nitrogen gases above 450. Transport information this product is not regulated as a hazardous material, substance or. Fluka 09682 page 1 of 7 sigmaaldrich material safety data sheet version 4. Skin contact liquid anhydrous ammonia produces skin burns on contact. Safety data sheet ammonia solution 24,9% section 1.
Material safety data sheet liquicop page 1 of 4 issue date. Safety data sheet ammonia, anhydrous section 1 linde gas. Liquid anhydrous ammonia produces skin burns on ingestion swallowing of the liquid results in severe corrosive action of the mouth, throat, and stomach. Ammonia is used in the production of liquid fertilizer solutions which consist of ammonia, ammonium nitrate, urea and aqua ammonia. Eyewash and safetyshower should be in immediate vicinity. Direct contact of the eyes with liquid anhydrous ammonia will produce serious eye burns. For large spills, cover liquid with protein foam 150 mm thick. Do not spray water directly on the leak or ammonia container. Always add caustic to water while stirring to prevent release of heat, steam, and fumes.
Ammonia solution 25% material safety data sheet sdsmsds. Anhydrous ammonia safety data sheet tanner industries. Identification of the substancemixture and of the companyundertaking date issued 05. Depending on the particular crop being grown, up to 200 pounds of ammonia per acre may be applied for each growing season. Material safety data sheet msds ammonia please ensure that this msds is received by the appropriate person afrox is a member of the linde group page 2 of 4 the stripe symbol and the word afrox are afrox group trademarks. Product and company identification chemical product liquicop epa reg. Ammonia gas may cause skin irritation, especially if skin is moist. When ammonia boils, it absorbs a tremendous amount of heat, which is why it is used as a refrigerant. Liquid ammonia may cause protective equipment to become brittle. Ammonia is a very valuable source of nitrogen that is essential for plant growth. Use of welding or flame cutting equipment on or in ammonia container is not recommended unless all ammonia has been purged, rinsed with water, and any oil residue removed. Atmospheric concentrations above 30,000 ppm will burn and blister skin after a few seconds of exposure. Msds ammonia cleaner version 1 72011 page 4 of 6 7 hargan road jet park, boksburg south africa tel.
Safety data sheet rochester institute of technology. A tractor tank semitrailer carrying 19 tons of liquid anhydrous ammonia accidentally went through a bridge rail on an interstate highway and fell about 5 m onto a freeway, on which, at the time of the accident, the traffic was quite heavy. Ammonia, anhydrous ammonia, ammonia n38, ammonia hg, ammonia. Liquid ammonia produces severe skin burns on contact. Page 1 of 8 material safety data sheet aqua ammonia 19% nh3 msds number 2050a revised february 16, 2007 8 pages 1. Large volumes of gas will evaporate from a liquid spill. Ammonia is a commonly used chemical in commercial and household cleaners. For small liquid spills, increase ventilation and allow the liquid to volatilise to safe area.
If liquid anhydrous ammonia has been swallowed, call a physician immediately. Instead, they changed the datum conditions at which enthalpy and entropy were zero. Material safety data sheet msds ammonia page 2 of 3 afrox is a member of the linde group page 2 of 3 the stripe symbol and the word afrox are afrox group trademarks. Safety data sheet according to 29cfr19101200 and ghs rev. Nitrogen, refrigerated liquid lin, cryogenic liquid nitrogen, liquid nitrogen, liquid nitrogen nf, liquid nitrogen fg liquefied gas safety data sheet. Anhydrous ammonia has potentially explosive reactions with strong oxidizers. Keep area evacuated and free from ignition sources until any spilled liquid has.
Show this safety data sheet to the doctor in attendance. Statement of health hazard is an irritant, and corrosive to skin, eye, respiratory tract and mucous membranes. Material safety data sheet anhydrous ammonia section 2. Anhydrous ammonia has a corrosive reaction with galvanized surfaces, copper, brass, bronze, aluminum alloys, mercury, gold and silver. Safety data sheet ammonia solution 24,9% fred holmberg. Aqua ammonia is listed as a hazardous substance under fwpca. In industry, ammonia is used in petroleum refining, to manufacture pharmaceuticals, to disinfect water, and as a refrigerant. Observe all warnings and precautions listed for the product use caution when combining with water. Based on its low boiling point and this absorption of heat, there is potential for frost or freeze burns if the liquid phase gets on skin. Msds product austin ammonia clear, sudzee, lemon, pine code 54200 page 3 of 4 section 8 exposure controls personal protection hygienic practices observe label precautions. The tank bleved and the liquid ammonia flashed off, forming a 30m high cloud.
For liquid ammonia contact, seek immediate medical attention. Appendix a thermodynamic property tables a2 ammonia data book may 2008 when the haar and gallagher data 1978 was released, ashrae chose not to simply update the old tables. Irrigate the nose and mouth continuously for 15 minutes. Engineering controls local exhaust ventilation may be required to keep vapors within exposure limits. Decomposition temperatures may be lowered by contact with certain metals. Hazardous identification hazardous ingredient wt% ammonia 99.
Ammonia concentrations in the range of 1625% by volume in air can be ignited if heated to the autoignition temperature. If inhaled if breathed in, move person into fresh air. Anhydrous ammonia an overview sciencedirect topics. Accidental release measures personal precautions, protective equipment, and emergency procedures. The odour recognition threshold for ammonia ranges from 0. Liquid ammonia is a useful solvent for many organic reactions including aliphatic and aromatic nucleophilic substitution and metalion catalysed reactions. Material safety data sheet msds ammonia please ensure that this msds is received by the appropriate person date. Runoff from fire control or dilution water may cause pollution.
First aid measures get medical attention immediately. Safety data sheet quaternary disinfectant cleaner 9496 5 cause ignition of organic vapors. Ammonia safety data sheet p4562 this sds conforms to u. Heating or addition of strong alkalis or bases can form an ignitable mixture with the air near the surface of the liquid. Material safety data sheet msds ammonia anhydrous cas no 7664 41 7. Anhydrous ammonia forms explosive mixtures in air with hydrocarbons, chlorine, fluorine and silver nitrate. Remove victim to fresh air and keep at rest in a position comfortable for breathing.
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